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Bernard L. Shaw : ウィキペディア英語版 | Bernard L. Shaw
Bernard L. Shaw, BSc, PhD, FRS is an English chemist who has made notable contributions to organometallic chemistry. He is Emeritus Professor of Inorganic and Structural Chemistry at the University of Leeds. ==Scientific contributions== Together with his longtime collaborator Joseph Chatt, Shaw contributed to the development of organoplatinum chemistry. They reported the first platinum hydride, PtHCl(PEt3)2. This colourless, volatile solid was the first non-organometallic hydride (i.e., lacking a metal-carbon bond).〔J. Chatt, L. A. Duncanson, B. L. Shaw "A Volatile Chlorohydride of Platinum" Proc. Chem. Soc., 1957, 329-368. 〕 With an interest in cyclometallation,〔Najeeb A. Al-Salem, H. David Empsall, Richard Markham, Bernard L. Shaw, Brian Weeks "Formation of large chelate rings and cyclometallated products from diphosphines of type But2P(CH2)nPBut2 (n= 5–8) and Ph2P(CH2)5PPh2 with palladium and platinum chlorides: factors affecting the stability and conformation of large chelate rings" J. Chem. Soc., Dalton Trans., 1979, 1972-1982. 〕 he discovered one of the first pincer complexes via the orthometalation of 1,3-C6H4(CH2PBut2)2.〔Christopher J. Moulton, Bernard L. Shaw "Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis()phenyl" J. Chem. Soc., Dalton Trans., 1976, 1020-1024. 〕
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